Hearts were drawn against Edinburgh rivals Hibernian as the Scottish Gas Women's Scottish Cup Third Round Draw took place at Hampden Park.
Scottish Olympic diver Grace Reid joined host Eilidh Barbour to conduct the draw at the National Stadium.
Holders Rangers were drawn away to Championship side Westdyke, while SWPL1 leaders Glasgow City were drawn away to Partick Thistle.
Celtic are away to Glasgow Girls & Women FC and Glenrothes Strollers - the only side to have made it all the way through from the first Preliminary Round - travel to Ainslie Park to face Spartans.
Reid has won gold at both the Commonwealth Games and European Championships during a glittering career. She also reached the final in the 3M Springboard category at this summer's Olympic Games in Paris, but she was unable to secure that elusive Olympic medal.
She reflected on her experiences at the games and Monday night's draw. She said: "I've not done any draws before so that was a new experience for me.
"My dad's a big Hearts fan so I was pleased to pull out an exciting draw like that. There's some exciting ties but that one is definitely worth a watch.
"It's the first time I've been back to Hampden since the Commonwealth Games Closing Ceremony so it's bringing back some good memories!
"I'm back in training now after a good break and the World Championships in Singapore is next on the horizon next year.
"It was so exciting to have an Olympics back to its best after Tokyo which was such a weird, disappointing experience with the pandemic. Paris is such a great city and the crowds were incredible. Walking out to a full stadium was just amazing.
"You didn't appreciate how important it is to have loud crowds and have your family there. I probably took it for granted a bit before. But having everyone there was one of the highlights of my career for sure.
"I know I'm capable of more and I'm frustrated I didn't show my best in the final but up until that point I'd been really consistent. By the time I got to the final I almost didn't have enough left in the tank so that's the main goal now to win a medal next year at the World Championships."
The full list of ties, which will be played on the weekend of Sunday, 8th December, is listed below.
Scottish Gas Women's Scottish Cup Third Round Draw
Aberdeen v Gartcairn
East Fife v Montrose
Elgin City v Dryburgh Athletic
Falkirk v Renfrew Ladies
Glasgow Girls & Women FC v Celtic
Greenock Morton v Bonnyrigg Rose
Heart of Midlothian v Hibernian
Inverness Caledonian Thistle v Dundee United
Livingston v Boroughmuir Thistle
Partick Thistle v Glasgow City
Queen’s Park v Hamilton Academical
Rossvale v Motherwell
Spartans v Glenrothes Strollers
St Johnstone v Ayr United
Stirling University v Kilmarnock
Westdyke v Rangers